Chemical transformation of 1,8-cineole: synthesis of seudenone, an insect pheromone
نویسندگان
چکیده
A simple method to transform the easily available 1,8-cineole (1) into the more valuable compound seudenone, 3-methyl-2-cyclohexenone (4), a sex pheromone of Dendroctonus pseudotsugae Hopkins, is described. © 2000 Elsevier Science B.V. All rights reserved.
منابع مشابه
Oxidation of 1,8-cineole, the monoterpene cyclic ether originated from eucalyptus polybractea, by cytochrome P450 3A enzymes in rat and human liver microsomes.
1,8-Cineole, the monoterpene cyclic ether known as eucalyptol, is one of the components in essential oils from Eucalyptus polybractea. We investigated the metabolism of 1,8-cineole by liver microsomes of rats and humans and by recombinant cytochrome P450 (P450 or CYP) enzymes in insect cells in which human P450 and NADPH-P450 reductase cDNAs had been introduced. 1,8-Cineole was found to be oxid...
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